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Synthetic approaches to physiologically active polycyclic compounds: VII. Synthesis of 2-(7-Hydroxybicyclo-[3.3.1]non-3-ylmethyl)propane-1,3-diol

✍ Scribed by O. N. Zefirova; E. V. Nurieva; V. N. Nuriev; A. A. Ivanov; N. V. Zyk; N. S. Zefirov


Book ID
111464759
Publisher
SP MAIK Nauka/Interperiodica
Year
2008
Tongue
English
Weight
225 KB
Volume
44
Category
Article
ISSN
1070-4280

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Intramolecular hydrosilation of ally1 and homoallyl alcohols and the subsequent oxidative cleavage of the resultant carbon-silicon bond have provided a new approach to the regio-controlled synthesis of 1,2-and/or 1,3-diols. We have recently developed a new methodology for the anti-Markownikoff hydra