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Synthetic approach towards tetrodotoxin. II. A stereospecific synthesis of a compound having the same six chiral centers on the cyclohexane ring as those of tetrodotoxin

✍ Scribed by Y. Kishi; F. Nakatsubo; M. Aratani; T. Goto; S. Inoue; H. Kakoi


Publisher
Elsevier Science
Year
1970
Tongue
French
Weight
238 KB
Volume
11
Category
Article
ISSN
0040-4039

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✦ Synopsis


In the preceding paper' we have reported a practical preparation of the Diels-Alder adduct II from S-(a-oximinoethyl)toluquinone and butadiene.

We would like to colmnunicate a derivation of II into XIX, which has the same six chiral centers on the cyclohexane ring as tetrodotoxin (I)

has.