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Synthetic applications of the cyclic iminocarbonate rearrangement: enantioselective syntheses of chloramphenicol and 4-epi-cytoxazone

✍ Scribed by Jung Nam Park; Soo Y. Ko; Hun Y. Koh

Book ID: 104210545
Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 122 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)00878-9

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✦ Synopsis

Chloramphenicol and 4-epi-cytoxazone have been enantioselectively synthesized using the asymmetric dihydroxylation and the cyclic iminocarbonate rearrangement as key steps.