Since their original conception by Corey and Seebaah, P-lithio-l,j\_dithianea have found widespread application in organic synthesis as masked carbonyl oompounds with a nuoleophilio central carbon atom. 2 Considerable broadening of the synthetic scope of 1,4\_dithianes might be expeoted if this carb
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Synthetic applications of 2-chloro-1,3-dithiane. 2. Reactions with carbon nucleophiles
โ Scribed by Kruse, C. G.; Wijsman, A.; Van der Gen, A.
- Book ID
- 120364318
- Publisher
- American Chemical Society
- Year
- 1979
- Tongue
- English
- Weight
- 613 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0022-3263
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dithiane derivatives R 0490 21 -142 1,3-Dithienium and 1,3-Dithiolenium Salts. Part 9. Reactions of 1,3-Dithiane-2-ylium Tetrafluoroborates with C-Nucleophiles. -New geminal disubstituted 1,3-dithianes, e.g. (III), (V), and (VII), are obtained by the title reaction. These compounds are potential pre