Synthetic application of phenylthio- and phenylsulfonylmethyl ethers to aldehydes, methylals, carboxylic acids, and enol or dienol ethers

✍ Scribed by Tadakatsu Mandai; Kiyomi Hara; Tsukasa Nakajima; Mikio Kawada; Junzo Otera

• Book ID: 104250283
• Publisher: Elsevier Science
• Year: 1983
• Tongue: French
• Weight: 206 KB
• Volume: 24
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)99830-2

✦ Synopsis

Carbon-carbon bond formation involving carbon homologation is one of the more important problems in synthetic organic chemistry. Above all, development of effective reagents for one carbon elongation has been the subject of extensive interest. In line with this, sulfur derivatives such as S,S-acetals (1,3-dithianes) and their S-oxides (FAMSO) have received considerable attention for these two decades. 1) However, these reagents are not always employable because metallic salts