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Synthetic and mechanistic aspects of palladium-catalyzed asymmetric hydrocyanation of alkenes. Crystal structure and reactions of (.eta.2-ethene)(diop)palladium

✍ Scribed by Hodgson, Martin.; Parker, David.; Taylor, Richard J.; Ferguson, George.


Book ID
115491926
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
862 KB
Volume
7
Category
Article
ISSN
0276-7333

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## Abstract magnified image Described herein is the development of a palladium(II)‐catalyzed two‐ or three‐component reaction of 2‐(1‐alkynyl)‐2‐alken‐1‐ones with nucleophiles and allylic chlorides. Various types of nucleophiles such as __O‐__, __N‐__, __C__‐based nucleophiles and olefin‐tethered