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Synthetic Analogues and Reaction Systems Relevant to the Molybdenum and Tungsten Oxotransferases

✍ Scribed by John H. Enemark; J. Jon A. Cooney; Jun-Jieh Wang; R. H. Holm


Publisher
John Wiley and Sons
Year
2004
Weight
52 KB
Volume
35
Category
Article
ISSN
0931-7597

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✍ Carmen Cuncillos Carmona; Sarah Clapham; Mathieu Gonidec; Vincent Ritleng; Pierr 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 475 KB

The reactions of selected primary amines with the unsaturatedheterodimetallic complex[(η-C 5 Me 5 )Ni(µ-CO)Mo(CO) 2 -(η-C 5 H 5 )](Ni-ត Mo) (1a) were investigated. Primary amines react with this heterodimetallic complex to form unstable adducts, which are in equilibrium with the free amine and compl