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SYNTHETIC ANALOGS OF CORTICAL HORMONES. I. HOMOGENTISIC ACID AND α,2,5-TRIHYDROXYACETOPHENONE DERIVATIVES FROM 2,5-DIACETOXY-α-DIAZOACETOPHENONE

✍ Scribed by KLOETZEL, MILTON C.; DAYTON, RHODES P.; ABADIR, B. Y.


Book ID
120712051
Publisher
American Chemical Society
Year
1955
Tongue
English
Weight
909 KB
Volume
20
Category
Article
ISSN
0022-3263

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β-Oxy-α-diazo-carbonyl compounds. Part 5
✍ Francisco Sarabia; Fidel Jorge López-Herrera 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 79 KB

Reactions of ethyl 2-diazoacetate with aldehydo sugars and monosaccharide derivatives in their hemiacetal form are reported. The use of diethyl zinc led to an improvement of yields and shorter reaction times compared with neutral conditions as previously described. The resulting products represent p