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Synthesis, X-ray studies, spectroscopic investigation, and DFT calculations of [ReBr3(dppt)(OPPh3)]

✍ Scribed by B. Machura; M. Wolff; A. Świtlicka; R. Kruszynski; J. Mroziński

Book ID
106538562
Publisher
Springer
Year
2010
Tongue
English
Weight
678 KB
Volume
21
Category
Article
ISSN
1040-0400

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The reactivity of [ReBr3(MeCN)(dppe)] towards gaseous nitric oxide. The X-ray structure of [ReBr3(MeCN)(dppe)] and [ReBr3(NO)(dppe)]0.57[ReOBr3(dppe)]0.43 and DFT calculations for [ReBr3(NO)(dppe)] and [ReOBr3(dppe)]
✍ B. Machura; R. Kruszynski; M. Jaworska 📂 Article 📅 2005 🏛 Elsevier Science 🌐 English ⚖ 361 KB

The [ReOBr 3 (dppe)] (dppeZbis(diphenylophosphino)ethane) complex reacts with acetonitrile in the presence of excess of triphenylphpsphine to give a new monomeric nitrile rhenium(III) complex-[ReBr 3 (MeCN)(dppe)] (1). The reaction of 1 with gaseous nitric oxide leads to the mixed [ReBr 3 (NO)(dppe)