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Synthesis, X-ray structure and luminescent properties of Sm3+ ternary complex with novel heterocyclic β-diketone and 1,10-phenanthroline (Phen)

✍ Scribed by Ilya V. Taydakov; Boris E. Zaitsev; Sergey S. Krasnoselskiy; Zoya A. Starikova

Book ID: 114337133
Publisher: Elsevier Science
Year: 2011
Tongue: English
Weight: 629 KB
Volume: 29
Category: Article
ISSN: 1002-0721
DOI: 10.1016/s1002-0721(10)60529-7

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Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 ´6 H 2 O were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A Ê