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Synthesis, x-ray diffraction structure, magnetic properties, and MO analysis of a binuclear (.mu.-tetrathiooxalato)copper(II) complex, (AsPh4)2[(C3OS4)CuC2S4Cu(C3OS4)]

✍ Scribed by Vicente, Ramon; Ribas, Joan; Alvarez, Santiago; Segui, Alex; Solans, Xavier; Verdaguer, Michel


Book ID
127146950
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
766 KB
Volume
26
Category
Article
ISSN
0020-1669

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First Complexes of a 4-Alkyl-3,5-di(2-py
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## Abstract The reaction of the new, bis(bidentate), potentially dinucleating ligand 4‐isobutyl‐3,5‐di(2‐pyridyl)‐4__H__‐1,2,4‐triazole (ibdpt) with M(ClO~4~)~2~Β·6H~2~O (M = Co^II^, Ni^II^ or Cu^II^) in a1:1 molar ratio in MeCN affords the dinuclear complexes [Co^II^~2~(ibdpt)~2~(MeCN)~2~(H~2~O)~2~