Synthesis, X-Ray Crystallography, and Reactions of N -Acyl and N -Carbamoyl Succinimides
β Scribed by Goodman, Cassie A.; Eagles, Joel B.; Rudahindwa, Leandre; Hamaker, Christopher G.; Hitchcock, Shawn R.
- Book ID
- 120460813
- Publisher
- Taylor and Francis Group
- Year
- 2013
- Tongue
- English
- Weight
- 454 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0039-7911
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## Abstract Selenocarboxylic acids [RC(=O)SeH] were found to readily react with aryl, acyl, and arenesulfonyl isocyanates to give the corresponding acyl carbamoyl selenides 3 [RC(=O)SeC(=O)NHRβ², Rβ² = aryl, C~6~H~5~CO, and 4βMeC~6~H~4~SO~2~] in good yields. Their tautomers [RC(=O)SeC(=NRβ²)OH] were a
## Abstract Of the isoelectronic 6βelectron systems **1a, 1b, 1c** __(Table 1)__ the deprotonated amides **2** might be useful derivatives for amine acidification (eq. (1)) if the carbonyl group is __sterically protected__ as shown in **3**. The tetrasubstituted succinimides **4, 5, 7, 8** and **9*