Synthesis, X-ray Crystal Structure and Magnetic Study of a μ1,5-dca Bridged Dimeric Copper(II) Complex
✍ Scribed by Dasarath Mal; Rupam Sen; Georgina M. Rosair; Subratanath Koner
- Publisher
- Springer
- Year
- 2011
- Tongue
- English
- Weight
- 318 KB
- Volume
- 41
- Category
- Article
- ISSN
- 1572-8854
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The synthesis, characterization and crystal structures of substituted imidazolate bridged binuclear copper(II) complexes, [Cu 2 (dien) 2 (L)](ClO 4 ) 3 , where dien ϭ diethylenetriamine, L ϭ imidazolate (im Ϫ ) (1), 2-methylimidazolate (mim Ϫ ) (2) and benzimidazolate (bim Ϫ ) (3), are reported. The
## Abstract The synthesis, X‐ray crystal structure and magnetic properties of two oxalato‐bridged dinuclear Cu^II^ complexes, [L‐Cu(μ‐ox)Cu‐L](ClO~4~)~2~, where ox = oxalate and L = 1,4,7‐trimethyl‐1,4,7‐triazacyclononane (Me~3~tacn) or 1‐benzyl‐4,7‐dimethyl‐1,4,7‐triazacyclononane (BzMe~2~tacn) ar