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Synthesis, X-ray crystal structure and complexation properties towards metal ions of new thiacalix[4]arenes

✍ Scribed by Roger Lamartine; Claude Bavoux; Francis Vocanson; Anna Martin; Gautier Senlis; Monique Perrin

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
83 KB
Volume
42
Category
Article
ISSN
0040-4039

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✦ Synopsis

p-tert-Butyl-tetrakis[(methylcarbonyl)methoxy]tetrathiacalix[4]arene and p-tert-butyl-tetrakis[(benzoyl)methoxy]tetra- thiacalix[4]

arene were prepared and their conformation was established by X-ray crystallography. p-tert-Butyl-tetrakis-[(diethylamide)methoxy]tetrathiacalix [4]arene was also synthesized. The ability of these three macrocycles to bind metal ions was investigated via a solvent extraction study.

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