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Synthesis Uses of Ynolates

โœ Scribed by Mitsuru Shindo


Publisher
John Wiley and Sons
Year
2007
Weight
11 KB
Volume
38
Category
Article
ISSN
0931-7597

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โœฆ Synopsis


Abstract

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๐Ÿ“œ SIMILAR VOLUMES


A synthesis of ynolates via the cleavage
โœ Mitsuru Shindo ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 199 KB

A new method for ynolate synthesis via the cleavage of ester dianions has been developed. The key intermediates, ester dianions, generated from ct-bromocarboxylic acid ester enolates via lithiumhalogen exchange turned out to be so labile that they were cleaved rapidly to give ynolates.