𝔖 Bobbio Scriptorium
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Synthesis, Structures, and Strain Energies of Dispirophosphiranes. Comparisons with Dispirocyclopropanes

✍ Scribed by Vlaar, Mark J. M.; Lor, Maarten H.; Ehlers, Andreas W.; Schakel, Marius; Lutz, Martin; Spek, Anthony L.; Lammertsma, Koop


Book ID
120514545
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
141 KB
Volume
67
Category
Article
ISSN
0022-3263

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Diiicrences between SiHS and CH; are more significant than the similarities. The proton affinity of Sib exceeds that of CH4 by ~25 kcal/mol. but the heat of hydrogenation of SiH; is smaller than that of CH: by nearly the mrne amount. Like CH:, the Cs structures of SiH: are preferred, but SiH: is bes