𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis, Structures, and Luminescent Properties of d10 Group 12 Metal Complexes with Substituted 2,2′-Bipyridine Ligands

✍ Scribed by Xiao-ming Liu; Xiao-yue Mu; Hong Xia; Ling Ye; Wei Gao; Hao-yu Wang; Ying Mu

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
188 KB
Volume
2006
Category
Article
ISSN
1434-1948

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

Four d^10^ group 12 metal complexes, 6‐(2‐methoxyphenyl)‐2,2′‐bipyridinezinc dichloride (2a), ‐mercury dichloride (2b), 6‐[2‐(dimethylamino)phenyl]‐2,2′‐bipyridinezinc dichloride (2c), and ‐mercury dichloride (2d), were synthesized and the structures determined by single‐crystal X‐ray crystallography. Complexes 2a and 2b are four‐coordinate and adopt a distorted tetrahedral geometry, while complexes 2c and 2d are five‐coordinate with a distorted trigonal bipyramidal geometry for the metal center. Luminescent properties of complexes 2a–2d in both solution and the solid state were studied. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

📜 SIMILAR VOLUMES

Synthesis and Structural Characterisatio
Synthesis and Structural Characterisation of Palladium and Group-12 Metal Complexes with a Hybrid Phosphanylphosphonate Ferrocene Ligand
✍ Petr Štěpnička; Ivana Císařová; Róbert Gyepes 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 295 KB

## Abstract Diethyl [1′‐(diphenylphosphanyl)ferrocenyl]phosphonate (1) was synthesised by stepwise metallation/functionalisation of 1,1′‐dibromoferrocene and studied as a ligand for palladium(II) and group‐12 metals. Treatment of [PdCl~2~(cod)] (cod = η^2^:η^2^‐cycloocta‐1,5‐diene) with 1 in 1:1 or