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Synthesis, Structures and DFT Calculations on Alkaline-Earth Metal Azide-Crown Ether Complexes

✍ Scribed by Michael D. Brown; Martin F. Davis; John M. Dyke; Francesco Ferrante; William Levason; J. Steven Ogden; Michael Webster


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
451 KB
Volume
14
Category
Article
ISSN
0947-6539

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An experimental method was developed to determine the stability constants with nearly insoluble ligands in homogeneous solution. This method was tested using dibenzo crown ethers, which have a very low solubility in aqueous solution. The stability constants for the complexation of alkali and alkalin