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Synthesis, structure, spectroscopic properties, and theoretical studies of a new blue/green luminescent complex: [Cd2Cl4(Hbm)2]n·nH2O (Hbm = 1H-benzimidazol-2-ylmethanol)

✍ Scribed by Ling Huang; Ai-Guo Zhong; Ding-Ben Chen; Hua-Ding Liang


Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
566 KB
Volume
922
Category
Article
ISSN
0022-2860

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A novel three-dimensional hybrid solid, [{(Cu 4 I 4 ) 2 H 2 O}{Cu 6 (mtz) 6 }] n (1) (Hmtz = 3,5-dimethyl-1,2,4-triazole), was synthesized under solvothermal condition. The structure of 1 consists of four-connected Cu 4 I 4 clusters and hexanuclear Cu 6 (mtz) 6 rings as secondary building units (SBU