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Synthesis, structure, spectroscopic and magnetic properties of a novel two-dimensional copper(II) complex Na2[Cu(pba)] · 6H2O [pba = 1,3-propylenebis(oxamato)]

✍ Scribed by Qing-Lun Wang; Bin Zhao; Dai-Zheng Liao; Shi-Ping Yan; Peng Cheng; Zong-Hui Jiang


Book ID
110430186
Publisher
Springer
Year
2003
Tongue
English
Weight
129 KB
Volume
28
Category
Article
ISSN
0340-4285

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Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 ´6 H 2 O were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A Ê