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Synthesis, structure, geometrical, and spectral characteristics of the (HLn)2[CuCl4] complexes. Crystal and molecular structure of bis(2-methylimidazolium) tetrachlorocuprate(II)

✍ Scribed by O. V. Kovalchukova; K. K. Palkina; S. B. Strashnova; B. E. Zaitsev


Book ID
111458251
Publisher
SP MAIK Nauka/Interperiodica
Year
2008
Tongue
English
Weight
246 KB
Volume
34
Category
Article
ISSN
1070-3284

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## Abstract In an attempt to synthesize a new pyrimidine complex of copper(II) in a solution reaction of CuBr~2~ with 2,2′‐bis(hexahydropyrimidine) and hydro‐chloric acid, we unexpectedly obtained a bright yellow chip‐like crystal of CuC~4~(H~2~tn) [H,tn=(H~3~NCH~2~CH~2~CH~2~NH~3~)^2+^]. Its struct