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Synthesis, structure and vibration spectra of the triple molybdates Tl5A0.5Hf1.5(MoO4)6, A = Ca, Sr, Ba, Pb

✍ Scribed by B.G. Bazarov; A.E. Sarapulova; R.F. Klevtsova; L.A. Glinskaya; K.N. Fedorov; Zh.G. Bazarova


Book ID
116601644
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
499 KB
Volume
448
Category
Article
ISSN
0925-8388

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✍ Yunlong Fu; Hui Lu πŸ“‚ Article πŸ“… 2008 πŸ› Elsevier Science 🌐 English βš– 382 KB

A novel three-dimensional hybrid solid, [{(Cu 4 I 4 ) 2 H 2 O}{Cu 6 (mtz) 6 }] n (1) (Hmtz = 3,5-dimethyl-1,2,4-triazole), was synthesized under solvothermal condition. The structure of 1 consists of four-connected Cu 4 I 4 clusters and hexanuclear Cu 6 (mtz) 6 rings as secondary building units (SBU