✦ LIBER ✦

Synthesis, structure and thermal decomposition of alinite

✍ Scribed by F.v. Lampe; W. Hilmer; K.H. Jost; G. Reck; A.I. Boikova

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 306 KB
Volume: 16
Category: Article
ISSN: 0008-8846
DOI: 10.1016/0008-8846(86)90088-8

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✦ Synopsis

Alinite was synthesized from CaCI~ fluxes containing MgO. Mg is essential and cannot b~ omitted. In contrast to the formula given by Ilyukhin et al. EPMA measurements revealed the composition Ca9.9Mgo. 800.3[Si3.4AI0.6016]01.9C11. 0 Spectroscopic and X-ray structure investigations favour the CaOA octahedra for substitution by Mg. [ro phase transformations were detected by DTA and X-raYodiffraction. The thermal decomposition begins at 1000 C, its rate depends strongly on the crystal size.

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