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Synthesis, Structure and Reactivity of Trimethylsilyl-Substituted Phosphametallocenes

✍ Scribed by Rebekka Loschen; Christoph Loschen; Walter Frank; Christian Ganter

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
185 KB
Volume
2007
Category
Article
ISSN
1434-1948

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Synthesis, structure, and reactivity of
Synthesis, structure, and reactivity of a symmetrically substituted 9-phosphatriptycene oxide and its derivatives
✍ Tomohiro Agou; Junji Kobayashi; Takayuki Kawashim πŸ“‚ Article πŸ“… 2004 πŸ› John Wiley and Sons 🌐 English βš– 167 KB

## Abstract Novel 9‐phosphatriptycenes were synthesized by utilizing ortho‐lithiation of a triarylphosphine oxide as a key step. The structural analysis of the 9‐phosphatriptycene oxide revealed its highly distorted structure around the phosphorus atom, which is consistent with the up‐field shift i