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Synthesis, Structure, and Reactivity of Stable PN Heterocycles with Two and Six Methyleneamine Units: [H2CNN(Me)]2 P(S)(Ph) and [H2CNN(Me)]6P3N3

✍ Scribed by Christophe Galliot; Dr. Anne-Marie Caminade; Dr. Françoise Dahan; Dr. Jean Pierre Majoral


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
376 KB
Volume
32
Category
Article
ISSN
0044-8249

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The ligands [Ph 2 (S)PNHP(X)Ph 2 ] -(X = O, Se) react with InCl 3 coordination geometry in 2 resembles that observed in the three analogous tris-chelates incorporating the corres-in a 3:1 ratio to give a tris-chelate [In{Ph 2 P(O)NP(S)Ph 2 -O,S} 3 ]•0.75 C 6 H 6 (2) and the unexpected pentacoordinat