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Synthesis, Structure, and Reactivity of Some N -Phosphorylphosphoranimines

✍ Scribed by Longlet, Jon J.; Bodige, Satish G.; Watson, William H.; Neilson, Robert H.

Book ID
127376084
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
144 KB
Volume
41
Category
Article
ISSN
0020-1669

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A new dioxodithiocarbamato compound of molybdenum(VI), MoO 2 (S 2 CNC 4 H 8 ) 2 (1), has been prepared and its reactivity towards substituted silanes, R 3 SiX (for R =Me, and X=Cl, Br, NCS, SO 3 Cl; R=n-Bu, X= Cl), HClO 4 and PPh 3 has been studied. The structure of 1 was determined by X-ray analysi