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Synthesis, Structure, and Reactivity of Ruthenium(II) Terminal Imido Complexes

✍ Scribed by Burrell, Anthony K.; Steedman, Andrew J.

Book ID
126424976
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
208 KB
Volume
16
Category
Article
ISSN
0276-7333

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A Base-Free Thorium–Terminal-Imido Metal
A Base-Free Thorium–Terminal-Imido Metallocene: Synthesis, Structure, and Reactivity
✍ Wenshan Ren; Prof. Guofu Zi; Prof. De-Cai Fang; Dr. Marc D. Walter πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons 🌐 English βš– 704 KB

The synthesis, structure, and reactivity of a base-free thorium terminal-imido metallocene have been comprehensively studied. Treatment of thorium metallocenes [{Ξ·(5)-1,2,4-(Me(3)C)(3)C(5)H(2)}(2)ThMe(2)] and [{Ξ·(5)-1,3-(Me(3)C)(2)C(5)H(3)}(2)ThMe(2)] with RNH(2) gives diamides [{Ξ·(5)-1,2,4-(Me(3)C)