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Synthesis, Structure, and Reactivity of Potassium Pyrazolato Complexes: The First Structurally Documented η 2 -Pyrazolato Coordination by a Main Group Metal

✍ Scribed by Yélamos, Carlos; Heeg, Mary Jane; Winter, Charles H.

Book ID: 127005415
Publisher: American Chemical Society
Year: 1998
Tongue: English
Weight: 56 KB
Volume: 37
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic980248d

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## Abstract Oxidation of the carboranyliridium fullerene complex [(η^2^‐C~60~)Ir(__o__‐HCB~10~H~9~CCH~2~PPh~2~‐__B__,__P__)(__t__BuNC)~2~] (I) in CHCl~3~ solution by O~2~ occurs by a selective insertion of the dioxygen molecule into the longest Ir−C bond (in the __trans__‐position relative to the B