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Synthesis, Structure, and Reactivity of (C5H4SiMe3)2Y{(μ-FC6F4)(μ-Me)B(C6F5)2}: Tight Ion Pairing in a Cationic Lanthanide Complex

✍ Scribed by Song, Xuejing; Thornton-Pett, Mark; Bochmann, Manfred

Book ID
111654775
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
173 KB
Volume
17
Category
Article
ISSN
0276-7333

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## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3