The synthesis, structure, and reactivity of a base-free thorium terminal-imido metallocene have been comprehensively studied. Treatment of thorium metallocenes [{η(5)-1,2,4-(Me(3)C)(3)C(5)H(2)}(2)ThMe(2)] and [{η(5)-1,3-(Me(3)C)(2)C(5)H(3)}(2)ThMe(2)] with RNH(2) gives diamides [{η(5)-1,2,4-(Me(3)C)
✦ LIBER ✦
Synthesis, Structure, and Reactivity of a Thorium Metallocene Containing a 2,2′-Bipyridyl Ligand
✍ Scribed by Ren, Wenshan; Zi, Guofu; Walter, Marc D.
- Book ID
- 126431353
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 949 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0276-7333
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