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Synthesis, Structure, and Reactions of Stable Oxametallacycles from Styrene Oxide on Ag(111) †

✍ Scribed by Enever, M.; Linic, S.; Uffalussy, K.; Vohs, J. M.; Barteau, M. A.

Book ID
125437832
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
138 KB
Volume
109
Category
Article
ISSN
0022-3654

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Preparation of zinc catalysts (Zn/PS-IL[X], X = Br -, Cl -, BF 4 -, and PF 6 -) supported on imidazolium-styrene copolymers, as well as their catalytic use for the solvent-free synthesis of styrene carbonate from CO 2 and styrene oxide, are described. Among the catalysts examined, Zn/PS-IL[Br] was p