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Synthesis, structure and properties of Sr3In11—optimizing the chemical bonding of hypoelectronic SrIn4

✍ Scribed by Jiang-Gao Mao; Arnold M. Guloy

Book ID
117622158
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
213 KB
Volume
363
Category
Article
ISSN
0925-8388

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The new compounds CaPdIn 2 , CaPtIn 2 , and CaAuIn 2 were prepared from the elements by reaction in glassy carbon crucibles under flowing argon. They crystallize with the MgCuAl 2 structure type (space group Cmcm), a ternary ordered version of the Re 3 B type. The three crystal structures were refin