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Synthesis, Structure, and Properties of BaAl2Si2.

✍ Scribed by Cathie L. Condron; Haakon Hope; Paula M. B. Piccoli; Arthur J. Schultz; Susan M. Kauzlarich


Publisher
John Wiley and Sons
Year
2007
Weight
19 KB
Volume
38
Category
Article
ISSN
0931-7597

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A new copper aluminum silicate CuAl 2 Si 2 O 7 (F,OH) 2 (cualsite) was synthesized hydrothermally from SiO 2 and Al 2 O 3 in a mineralizing solution 1 3 Na 3 AlF 6 Ψ‰ 4 9 Al(NO 3 ) 3 Ψ‰ 1 9 Cu(NO 3 ) 2 Ψ‰ 27.8H 2 O at 600Β°C and 150 MPa. Cualsite grew epitaxially on the pinacoidal plane of the topaz si