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Synthesis, Structure, and Polymerization Activity of a Titanium Complex with a Chelating [(Hydroxy-κO)amino-κN]phenolato(2−)-κO Ligand

✍ Scribed by Bradley M. Kraft; Kuo-Wei Huang; Adam P. Cole; Robert M. Waymouth

Publisher: John Wiley and Sons
Year: 2006
Tongue: German
Weight: 91 KB
Volume: 89
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.200690159

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✦ Synopsis

Abstract

A novel titanium complex with a chelating nitroxide ligand, dichloro‐2‐{[(hydroxy‐κO)phenylamino‐κN)phenylmethyl}phenolato(2−)‐2__κO__}(tetrahydrofuran)titanium (1), was synthesized and characterized by NMR spectroscopy, elemental analysis, and single‐crystal X‐ray crystallography. In the presence of methylaluminoxane (MAO), 1 displayed moderate activity for the polymerization of propylene.

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