Synthesis, Structure, and Physicochemical Investigations of the New α Cu0.50TiO(PO4) Oxyphosphate.
✍ Scribed by S. Benmokhtar; H. Belmal; A. El Jazouli; J. P. Chaminade; P. Gravereau; S. Pechev; J. C. Grenier; G. Villeneuve; D. de Waal
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 14 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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A new iron titanyl oxyphosphate Fe 0.50 TiO(PO 4 ) was synthesized by both solid-state reaction and Cu 2+ -Fe 2+ ion exchange method. The material was then characterized by X-ray diffraction, Mo¨ssbauer spectroscopy, magnetic susceptibility measurements and Raman spectroscopy. The crystal structure
Single crystals of a new bismuth oxyphosphate were isolated and X-ray investigated, leading to the formula Bi 6.67 (PO 4 ) 4 O 4 . Its crystal structure was refined using 2624 independent reflections in the P1 space group, a ؍ 9.195(15) A s , b ؍ 7.552(5) A s , c ؍ 6.933(4) A s , ؍ 112.2(1)°