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Synthesis, Structure, and Physical Properties of a Novel Quaternary Niobium Telluride, Nb2FeCu0.35Te4

✍ Scribed by Li, Jing; McCulley, Frank; Dioszeghy, Mark J.; Chen, S. C.; Ramanujachary, K. V.; Greenblatt, M.


Book ID
126215690
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
672 KB
Volume
33
Category
Article
ISSN
0020-1669

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Rb 12 Nb 6 Se 35 is the first ternary niobium polyselenide composed of infinite anionic chains. These are well separated by rubidium cations. It crystallizes in the orthorhombic space group Pbcn with unit cell dimensions a ‫؍‬ 8.5811(1) A s , b ‫؍‬ 13.7152(1) A s , c ‫؍‬ 56.5225(4) A s , and Z ‫؍‬ 4