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Synthesis, Structure and Photochemical Properties of 4, 4′, 7, 7′-Tetra-substituted 1,1′, 3,3′-Tetraethylbenzimidazolotriazatrimethine Cyanines

✍ Scribed by Rudolf Naef; Heinz Balli


Publisher
John Wiley and Sons
Year
1978
Tongue
German
Weight
839 KB
Volume
61
Category
Article
ISSN
0018-019X

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✦ Synopsis


Abstract

The synthesis of sterically hindered 1,1′, 3,3′‐tetraethylbenzimidazolotriazatrimethine cyanine dyes, their electron absorption spectra and that of their photo‐products (inverse photochromism) is described. Kinetic data of the thermally reversed reaction of the photo‐bleached compounds are given. The differences of the electron absorption spectra in this series in this series of dyes are explained by the different degree of distortion of the π‐systems which is confirmed by an X‐ray investigation.


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