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Synthesis, structure and oxygen nonstoichiometry of La0.4Sr0.6Co1−yFeyO3−δ

✍ Scribed by V.A. Cherepanov; L.Ya. Gavrilova; T.V. Aksenova; M.V. Ananyev; E. Bucher; G. Caraman; W. Sitte; V.I. Voronin

Book ID
116847844
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
591 KB
Volume
35
Category
Article
ISSN
0079-6786

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Thermodynamic Quantities and Defect Stru
Thermodynamic Quantities and Defect Structure of La0.6Sr0.4Co1−yFeyO3−δ(y=0–0.6) from High-Temperature Coulometric Titration Experiments
✍ M.H.R. Lankhorst; J.E. ten Elshof 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 366 KB

The partial energies and entropies of O 2 in perovskite-type oxides La 0.6 Sr 0.4 Co 1؊y Fe y O 3؊ ( y ‫؍‬ 0, 0.1, 0.25, 0.4, 0.6) were determined as a function of nonstoichiometry by coulometric titration of oxygen in the temperature range 650-950°C. An absolute reference value of was obtained by t