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Synthesis, structure and oxidative addition reactions of triscyclopentadienyluranium(III) nitrile complexes

✍ Scribed by Raymond Adam; Claude Villiers; Michel Ephritikhine; Monique Lance; Martine Nierlich; Julien Vigner


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
685 KB
Volume
445
Category
Article
ISSN
0022-328X

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## The addition reactions of diatomic molecules, X-Y (X-Y = HCl, HBr, HI, Cl? and BrJ to squareplanar d0 carborane-iridium(I) complexes of general formula trans-[Ir(o-carb)(CO)L,], where L = PPh3, PMePhz and carb = -2-R-1,2-and -7-R-I,7-BlO-CzHlo (R = H, CH,, CJI,) have been investigated in both the