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Synthesis, Structure, and Olefin Polymerization Catalytic Behavior of Aryl-Substituted Zirconocene Dichlorides

✍ Scribed by Thornberry, Matthew P.; Reynolds, Nathan T.; Deck, Paul A.; Fronczek, Frank R.; Rheingold, Arnold L.; Liable-Sands, Louise M.


Book ID
120464142
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
124 KB
Volume
23
Category
Article
ISSN
0276-7333

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## Abstract The syntheses of a series of l‐methyl‐3‐aryl‐substituted titanocene and zirconocene dichlorides are reported. These complexes are synthesized by the reaction of 2‐ and 3‐methyl‐6, 6‐dimethylfulvenes (1:4) with aryllithium, followed by the reaction with TiCl~4~Β·2THF, ZrCl~4~ and (CpTiCl~