Synthesis, structure, and magnetism of two tetrahalocuprate salts: (5-TFAPH)2CuX4 (5-TFAP=2-amino-5-trifluoromethylpyridine, X=Cl, Br)
β Scribed by Gale, Alexander J.; Landee, Christopher P.; Turnbull, Mark M.; Wikaira, Jan L.
- Book ID
- 122787139
- Publisher
- Elsevier Science
- Year
- 2013
- Tongue
- English
- Weight
- 646 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0277-5387
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Bis(disulfide) bridged Nb(+4) cluster halide complexes [Nb 2 S 4 X 8 ] 4Β± (X = Cl, Br) were prepared by acid hydrolysis of [Nb 2 S 4 (NCS) 8 ] 4Β± in concentrated aqueous HCl or HBr, solution from which they can be isolated as double salts Cs 5 [Nb 2 S 4 X 8 ]X (X = Cl, 1; X = Br, 2). The crystal st