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Synthesis, Structure, and Magnetism of a Polyoxometalate with Coordinatively Unsaturated d-Electron-Transition Metal Centers

✍ Scribed by Luo, Zhen; Kögerler, Paul; Cao, Rui; Hill, Craig L.

Book ID
120532021
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
751 KB
Volume
48
Category
Article
ISSN
0020-1669

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## Abstract The podand ligand tris(4‐carboxy‐2‐phenoxyethyl)amine (ptaH~3~) readily reacts with Co^II^, Mn^II^ and Ni^II^ salts at room temperature to afford porous coordination polymers, {Co(ptaH)·5H~2~O}__~n~__ (1), {[Mn(ptaH)(H~2~O)]·4H~2~O}__~n~__ (2), and {[Ni(ptaH)(4H~2~O)]·6H~2~O}__~n~__, (3