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Synthesis, structure and magnetic properties of oxalate-bridged complex [Cu2(bpy)2(C2O4)(H2O2)][Cu(bpy)(C2O4)](NO3)2

✍ Scribed by Juan Shi; Guang-Ming Yang; Peng Cheng; Dai-Zheng Liao; Zong-Hui Jiang; Geng-Lin Wang


Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
241 KB
Volume
16
Category
Article
ISSN
0277-5387

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A heterometallic Zn,Nb compound of the formula [{Zn(bpy) 2 } 2 (l-C 2 O 4 )][Zn(bpy) 2 (l-C 2 O 4 )NbO(C 2 O 4 ) 2 ] 2 Á0.5bpyÁ7H 2 O (1) (bpy = 2,2 0 -bipyridine) has been synthesized by the reaction of the tris(oxalato)oxoniobate(V) anion, [NbO(C 2 O 4 ) 3 ] 3Γ€ and [Zn(bpy) 3 ] 2+ in an aqueous so