Synthesis, Structure and Magnetic Properties of a Novel Linear CuII-Trimer Complex
✍ Scribed by Vladimir Pashchenko; Bernhard Brendel; Bernd Wolf; Michael Lang; Konstantin Lyssenko; Olga Shchegolikhina; Yulia Molodtsova; Larisa Zherlitsyna; Norbert Auner; Florian Schütz; Marcus Kollar; Peter Kopietz; Neil Harrison
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 208 KB
- Volume
- 2005
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The phenoxo‐bridged dinuclear Cu^II^ complex [Cu~2~L~2~(NCNCN)~2~] (1) and the dicyanamide‐bridged molecular rectangle [Cu~4~L~4~{μ~1,5~‐(NCNCN)~2~}]·(ClO~4~)~2~(H~2~O)~2~ (2) were synthesized using the tridentate reduced Schiff‐base ligand HL {2‐[(2‐dimethylamino‐ethylamino)methyl]phen
Three new copper(II) linear trinuclear compounds are crystallise in the triclinic space group P-1 with a = 8.529( 5), b = 15.760(5), c = 19.639(5) A ˚, α = 101.793(5), β = 101.263(5), reported, all of which were synthesized in-situ, with the general formula [Cu 3 (L) 4 ](CF 3 SO 3 ) 2 (Y) x , where