## Abstract For Abstract see ChemInform Abstract in Full Text.
Synthesis, Structure and Magnetic Properties of a New Iron Arsenate, [C10N4H28][{FeF(OH)(HAsO4)}4], with a Layer Structure
✍ Scribed by Sandip Chakrabarti; Swapan K. Pati; Mark A. Green; Srinivasan Natarajan
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 174 KB
- Volume
- 2003
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The reaction of FeCl~3~·6H~2~O, H~3~AsO~4~, HF and 1,4‐bis(3‐aminopropyl)piperazine under solvothermal conditions gives rise to a new iron arsenate, [C~10~N~4~H~28~][{FeF(OH)(HAsO~4~)}~4~] (I) with a layered structure. The cell parameters are monoclinic, space group = __P__2~1~/__n__ (n
A new zinc phosphate, (C 10 N 4 H 28 )[Zn 6 (HPO 4 ) 2 (PO 4 ) 4 ] ' 2H 2 O, with a layered architecture has been synthesized, for the 5rst time, in the presence of 1,4-bis(3-aminopropyl)piperazine as the structure-directing agent. The structure comprises a network of ZnO 4 and phosphate tetrahedra
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