Synthesis, structure and luminescent property of a 2D polymer containing silver ions

✍ Scribed by Bin Zhao; Xiao-Qing Zhao; Wei Shi; Peng Cheng

• Publisher: Elsevier Science
• Year: 2007
• Tongue: English
• Weight: 318 KB
• Volume: 830
• Category: Article
• ISSN: 0022-2860
• DOI: 10.1016/j.molstruc.2006.07.007

✦ Synopsis

Silver(I) complex with 4,5-dicarboxyimidazole (H 3 dcbi) has been synthesized by hydrothermal method and proven to be a novel 2D coordination polymer [Ag(H 2 dcbi)] n (1), which crystallized in monoclinic crystal system and space group of P2(1)/c. Each Ag(I) ion is coordinated to three O atoms and one N atom, which completes the trigonal pyramidal geometry of Ag(I) ion. Solid-state fluorescent emission spectra of 1 were investigated.