Two lanthanide benzenedicarboxylates, [La 2 (isophth) isophth = isophthalic acid, Ac = acetate) have been obtained by hydrothermal synthetic method and characterized by elementary analysis, IR, TG, and especially the X-rays single-crystal diffraction. The complexes 1 and 2 crystallize in the monocl
Synthesis, structure and luminescence of novel 1D chain coordination polymers [Ln(isophth)(Hisophth)(H2O)4·4H2O]n (Ln=Sm, Dy)
✍ Scribed by Bing Yan; Yingying Bai; Zhenxia Chen
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 284 KB
- Volume
- 741
- Category
- Article
- ISSN
- 0022-2860
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Single crystals of a new sodium ytterbium oxalate Na[Yb(C 2 O 4 ) 2 (H 2 O)] Á 3H 2 O (1) and six mixed lanthanide (III)-uranium (IV) oxalates (NH 4 6) and Ln ¼ Tb, x ¼ 0:52 (7) have been grown using slow diffusion through silica gels. The crystal structures of all the compounds have been determined