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Synthesis, Structure, and Ion Pair Dynamics of β-Diketiminato-Supported Organoscandium Contact Ion Pairs

✍ Scribed by Hayes, Paul G.; Piers, Warren E.; Parvez, Masood

Book ID
121465054
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
334 KB
Volume
24
Category
Article
ISSN
0276-7333

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Arene Complexes of β-Diketiminato Supported Organoscandium Cations: Mechanism of Arene Exchange and Alkyne Insertion in Solvent Separated Ion Pairs
✍ Paul G. Hayes; Warren E. Piers; Masood Parvez 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 229 KB 👁 1 views

## Abstract A family of isolable solvent separated organoscandium methyl cations stabilized by β‐diketiminato ligands (Ar)NC(CH~3~)CHC(CH~3~)N(Ar) (Ar=2,6‐__i__Pr‐C~6~H~3~, L^Me^) has been prepared by reaction of L^Me^ScR~2~ with [CPh~3~][B(C~6~F~5~)~4~] in the presence of an arene solvent. Arenes