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Synthesis, structure and electrical properties of the two-dimensional organic conductor, (BEDT-TTF)2BrI2

✍ Scribed by Zhu Daoben; Wang Ping; Wan Meixiang; Yu Zhaolou; Zhu Nailue; S. Gärnier; D. Schweitzer


Publisher
Elsevier Science
Year
1986
Weight
184 KB
Volume
143
Category
Article
ISSN
0378-4363

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✦ Synopsis


Single crystals of ~-(BEDT-TTF)2Brl 2 and B-(BEDT-TTF)2Brl 2 were prepared using standard electrochemical techniques in nitrogen saturated benzonitrile solution containing (n-C4HIo)NBrl 2 as supporting electrolyte. The crystals have nearly identical structure features of ~-(BEDT-TTF)213 and B-(BEDT-TTF)213, except that the BrI2 anions are disordered in ~-(BEDT-TTF)2Brl 2 and B-(BEDT-TTF)2Brl 2. Their electrical behavior is different from the corresponding ~-,B-(BEDT-TTF)213species.


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