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Synthesis, structure and DNA-binding studies on the 2-(3-chlorophenyl)imidazo[4,5-f]1,10-phenanthroline-bis(2,2′-bipy ridine)-ruthenium(II) complex

✍ Scribed by Ya Xiong; Xiao-Hua Zou; Jian-Zhong Wu; Liang-Nian Ji; Run-Hua Li; Jian-Ying Zhou; Kai-Bei Yu

Book ID
110244453
Publisher
Springer
Year
1999
Tongue
English
Weight
137 KB
Volume
24
Category
Article
ISSN
0340-4285

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Two new chiral ruthenium(II) complexes D-[Ru(bpy) 2 (nfip)] 2+ and K-[Ru(bpy) 2 (nfip)] 2+ (in which bpy = 2,2 0 -bipyridine, nfip = 2-(5-nitrofuran-2-yl)-1H-imidazo[4,5-f][1,10]phenanthroline) have been synthesized and characterized by elemental analysis, ES-MS, 1 H NMR and CD spectra. The binding

Synthesis, Characterization, and DNA Int
Synthesis, Characterization, and DNA Interaction Studies of the Ruthenium(II) Complexes [Ru(bpy)2(ipbp)]2+ and [Ru(ipbp)(phen)2]2+ (ipbp=3-(1H-Imidazo[4,5-f][1,10]phenanthrolin-2-yl)-4H-1-benzopyran-2-one; bpy=2,2′-Bipyridine; phen=1,10-Phenanthroline)
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## Abstract A novel ligand 3‐(1__H__‐imidazo[4,5‐__f__][1,10]phenanthrolin‐2‐yl)‐4__H__‐1‐benzopyran‐4‐one (ipbp) and its ruthenium(II) complexes [Ru(bpy)~2~(ipbp)]^2+^ (**1**) and [Ru(ipbp)(phen)~2~]^2+^ (**2**) (bpy=2,2′‐bipyridine, phen=1,10‐phenanthroline) were synthesized and characterized by